Download PDF by H. Miyamoto, M. Salomon, H. L. Clever: Alkaline Earth Metal Halates

By H. Miyamoto, M. Salomon, H. L. Clever

Solubilities of the chlorates, bromates and iodates of the alkaline earth metals (magnesium, calcium, strontium and barium) in all liquid solvents are awarded in tabular structure and significantly evaluated. this is often the 1st of 4 volumes within the sequence protecting the inorganic halates, and gives crucial info on those very important commercial reagents.

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260. 256. 249. 240. 15 268, 291, 292, 293. 298, 346. 06 9. 15 9, 18 9. 51 15. 2 17. 19. 22. 27. 1 55 It Ca(C10 3 ) 2 '6H 2 0 + Ca(C10 3 ) 2 ·4Η 2 0 Ca(Cl0 3 )2-4H 2 0 Ca(C10 3 ) 2 *4H 2 0 + Ca(C10 3 ) 2 -2H 2 0 Ca(Cl0 3 )2'2H 2 0 Ca(C10 3 ) 2 -2H 2 0 + Ca(C10 3 ) 2 Ca(Cl0 3 ) 2 m : experimental value W calculated value 2. Ternary and quaternary systems Solubility in ternary Ca(ClO^)^-CaCl^-H^O system. 2K, respectively. Double salts in this system were not formed. Solubility in ternary Ca(CIO3)2-KCIO3-H2O system.

The result has been reported in 2 publications (2,3). 0005 mol k g - 1 . The mean is a recommended value. 2K (solid phase: tetrahydrate). in (T) obtained by Mylius and Funk is higher than that of other investigators (2). It is felt the data in (2) are more accurate, therefore, the result of Mylius and Funk is rejected. 1733 mol k g " 1 . 2K (solid phase: tetrahydrate). This result has The result reported in (1) been reported in 2 publications (1,2). obtained by Mylius and Funk is considerably lower than that of Hill and Moskowitz (2).

Soc. by p e r m i s s i o n of t h e c o p y r i g h t o w n e r s , The American Chemical S o c i e t y . 23 Ternary aqueous systems COMPONENTS: (1) M a g n e s i u m i o d a t e ; [7790-32-1] (2) I o d i c a c i d ; H I 0 3 ; (3) W a t e r ; H 2 0 ; ORIGINAL MEASUREMENTS: V i n o g r a d o v , E. E . ; A z a r o v a , L. A. MgilO^)^; Zh. Neorg. Khim, 1911, Russ. J, Inorg. Chem. 1 9 7 7 , 22, 903-5. [7782-68-5] [7732-18-5] VARIABLES: 22, 1666-8; (Engt. 63 Nature of the Solid Phase a A A A A A A A A A + B A + B B B B B A = Mg(I0 3 ) 2 ·4Η 2 0; B = HI0 3 .

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